Washington, Jan 10: American actress Angelina Jolie was caught with a big scowl on her face after Anne Hathaway was awarded Best Actress on January 8 at the VH1 Critics Choice Awards.

Jolie, who had been all smiles before the announcement, was spotted on camera twice sporting a severe scowl.

"Angelina didn't say much for the rest of the night," Fox News quoted an eyewitness as saying.

"She was all smiles before the announcement, and it was clear she wasn't happy," the eyewitness added.

Meanwhile, Hathaway, who won the award for her performance in "Rachel Getting Married", shared the honour with "Doubt" actress Meryl Streep.

She just could not stop gushing about how thrilled she was to win something with her idol. (ANI)